Nihonium (113Nh) is a synthetic element. Being synthetic, a standard atomic weight cannot be given and like all artificial elements, it has no stable isotopes. The first isotope to be synthesized was 284Nh as a decay product of 288Mc in 2003. The first isotope to be directly synthesized was 278Nh in 2004. There are 6 known radioisotopes from 278Nh to 286Nh, along with the unconfirmed 287Nh and 290Nh. The longest-lived isotope is 286Nh with a half-life of 9.5 seconds.
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List of isotopes
| Nuclide | Z | N | Isotopic mass (Da) [n 1][n 2] | Half-life | Decay mode [n 3] | Daughter isotope | Spin and parity | ||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 278Nh[4] | 113 | 165 | 278.17058(20)# | 2.0+2.7 −0.7 ms | α | 274Rg | |||||||||||||
| 282Nh | 113 | 169 | 282.17567(39)# | 61+73 −22 ms[5] | α | 278Rg | |||||||||||||
| 283Nh[n 4] | 113 | 170 | 283.17657(52)# | 123+80 −35 ms[5] | α | 279Rg | |||||||||||||
| 284Nh[n 5] | 113 | 171 | 284.17873(62)# | 0.90+0.07 −0.06 s[5] | α (≥99%) | 280Rg | |||||||||||||
| EC (≤1%)[5] | 284Cn | ||||||||||||||||||
| 285Nh[n 6] | 113 | 172 | 285.17973(89)# | 2.1+0.6 −0.3 s[5] | α (82%) | 281Rg | |||||||||||||
| SF (18%)[5] | (various) | ||||||||||||||||||
| 286Nh[n 7] | 113 | 173 | 286.18221(72)# | 9.5 s | α | 282Rg | |||||||||||||
| 287Nh[n 8] | 113 | 174 | 287.18339(81)# | 5.5 s | α | 283Rg | |||||||||||||
| 290Nh[n 9] | 113 | 177 | 2 s? | α | 286Rg | ||||||||||||||
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Isotopes and nuclear properties
Nucleosynthesis
Super-heavy elements such as nihonium are produced by bombarding lighter elements in particle accelerators that induce fusion reactions. Whereas most of the isotopes of nihonium can be synthesized directly this way, some heavier ones have only been observed as decay products of elements with higher atomic numbers.[6]
Depending on the energies involved, the former are separated into "hot" and "cold". In hot fusion reactions, very light, high-energy projectiles are accelerated toward very heavy targets (actinides), giving rise to compound nuclei at high excitation energy (~40–50 MeV) that may either fission or evaporate several (3 to 5) neutrons.[7] In cold fusion reactions, the produced fused nuclei have a relatively low excitation energy (~10–20 MeV), which decreases the probability that these products will undergo fission reactions. As the fused nuclei cool to the ground state, they require emission of only one or two neutrons, and thus, allows for the generation of more neutron-rich products.[6] The latter is a distinct concept from that of where nuclear fusion claimed to be achieved at room temperature conditions (see cold fusion).[8]
Cold fusion
Before the synthesis of nihonium by the RIKEN team, scientists at the Institute for Heavy Ion Research (Gesellschaft für Schwerionenforschung) in Darmstadt, Germany also tried to synthesize nihonium by bombarding bismuth-209 with zinc-70 in 1998. No nihonium atoms were identified in two separate runs of the reaction.[9] They repeated the experiment in 2003 again without success.[9] In late 2003, the emerging team at RIKEN using their efficient apparatus GARIS attempted the reaction and reached a limit of 140 fb. In December 2003 – August 2004, they resorted to "brute force" and carried out the reaction for a period of eight months. They were able to detect a single atom of 278Nh.[10] They repeated the reaction in several runs in 2005 and were able to synthesize a second atom,[11] followed by a third in 2012.[12]
The table below contains various combinations of targets and projectiles which could be used to form compound nuclei with Z=113.
| Target | Projectile | CN | Attempt result |
|---|---|---|---|
| 208Pb | 71Ga | 279Nh | Reaction yet to be attempted |
| 209Bi | 70Zn | 279Nh | Successful reaction |
| 238U | 45Sc | 283Nh | Reaction yet to be attempted |
| 237Np | 48Ca | 285Nh | Successful reaction |
| 244Pu | 41K | 285Nh | Reaction yet to be attempted |
| 250Cm | 37Cl | 287Nh | Reaction yet to be attempted |
| 248Cm | 37Cl | 285Nh | Reaction yet to be attempted |
Hot fusion
In June 2006, the Dubna-Livermore team synthesised nihonium directly by bombarding a neptunium-237 target with accelerated calcium-48 nuclei, in a search for the lighter isotopes 281Nh and 282Nh and their decay products, to provide insight into the stabilizing effects of the closed neutron shells at N = 162 and N = 184:[13]
Two atoms of 282Nh were detected.[13]
As decay product
| Evaporation residue | Observed nihonium isotope |
|---|---|
| 294Lv, 290Fl ? | 290Nh ?[3] |
| 287Fl ? | 287Nh ?[14] |
| 294Ts, 290Mc | 286Nh[15] |
| 293Ts, 289Mc | 285Nh[15] |
| 288Mc | 284Nh[16] |
| 287Mc | 283Nh[16] |
| 286Mc | 282Nh |
Nihonium has been observed as a decay product of moscovium (via alpha decay). Moscovium currently has five known isotopes; all of them undergo alpha decays to become nihonium nuclei, with mass numbers between 282 and 286. Parent moscovium nuclei can be themselves decay products of tennessine. It may also occur as a decay product of flerovium (via electron capture), and parent flerovium nuclei can be themselves decay products of livermorium.[17] For example, in January 2010, the Dubna team (JINR) identified nihonium-286 as a product in the decay of tennessine via an alpha decay sequence:[15]
Theoretical calculations
Evaporation residue cross sections
The below table contains various targets-projectile combinations for which calculations have provided estimates for cross section yields from various neutron evaporation channels. The channel with the highest expected yield is given.
DNS = Di-nuclear system; σ = cross section
| Target | Projectile | CN | Channel (product) | σmax | Model | Ref |
|---|---|---|---|---|---|---|
| 209Bi | 70Zn | 279Nh | 1n (278Nh) | 30 fb | DNS | [18] |
| 238U | 45Sc | 283Nh | 3n (280Nh) | 20 fb | DNS | [19] |
| 237Np | 48Ca | 285Nh | 3n (282Nh) | 0.4 pb | DNS | [20] |
| 244Pu | 41K | 285Nh | 3n (282Nh) | 42.2 fb | DNS | [19] |
| 250Cm | 37Cl | 287Nh | 4n (283Nh) | 0.594 pb | DNS | [19] |
| 248Cm | 37Cl | 285Nh | 3n (282Nh) | 0.26 pb | DNS | [19] |
References
- Isotope masses from:
- M. Wang; G. Audi; A. H. Wapstra; F. G. Kondev; M. MacCormick; X. Xu; et al. (2012). "The AME2012 atomic mass evaluation (II). Tables, graphs and references" (PDF). Chinese Physics C. 36 (12): 1603–2014. Bibcode:2012ChPhC..36....3M. doi:10.1088/1674-1137/36/12/003. S2CID 250839471.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- Half-life, spin, and isomer data selected from the following sources.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
- Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). CRC Handbook of Chemistry and Physics (85th ed.). Boca Raton, Florida: CRC Press. ISBN 978-0-8493-0485-9.