Philipp Petzschner and Tim Pütz were the defending champions, but Petzschner chose not to participate this year. Pütz played alongside Jan-Lennard Struff, but lost in the first round to John Peers and Bruno Soares.
| Doubles | |
|---|---|
| 2019 MercedesCup | |
| Champions |  John Peers Bruno Soares |
| Runners-up |  Rohan Bopanna Denis Shapovalov |
| Score | 7–5, 6–3 |
| Draw | 16 |
| Seeds | 4 |
Peers and Soares went on to win the title, defeating Rohan Bopanna and Denis Shapovalov in the final, 7–5, 6–3.
Seeds
John Peers / 
Bruno Soares (champions)
Nikola Mektić / Franko Škugor (first round)
Bob Bryan / Mike Bryan (first round)
Oliver Marach / Jürgen Melzer (semifinals)
Draw
Key
- Q = Qualifier
- WC = Wild card
- LL = Lucky loser
- Alt = Alternate
- SE = Special exempt
- PR = Protected ranking
- ITF = ITF entry
- JE = Junior exempt
- w/o = Walkover
- r = Retired
- d = Defaulted
- SR = Special ranking
Draw
| First round | Quarterfinals | Semifinals | Final | ||||||||||||||||||||||||
| 1 | J Peers B Soares | 4 | 7 | [10] | |||||||||||||||||||||||
 T Pütz J-L Struff | 6 | 5 | [6] | 1 | J Peers B Soares | 6 | 77 | ||||||||||||||||||||
| M Demoliner D Sharan | 7 | 614 | [9] |  D Molchanov A Sitak | 3 | 65 | |||||||||||||||||||||
| D Molchanov A Sitak | 5 | 716 | [11] | 1 | J Peers B Soares | 77 | 5 | [10] | |||||||||||||||||||
| 4 |  O Marach J Melzer | 77 | 6 | 4 | O Marach J Melzer | 64 | 7 | [6] | |||||||||||||||||||
| A Zverev M Zverev | 65 | 3 | 4 | O Marach J Melzer | 6 | 6 | |||||||||||||||||||||
 S Johnson G Simon | 3 | 5 |  R Lindstedt M Raonic | 2 | 4 | ||||||||||||||||||||||
| R Lindstedt M Raonic | 6 | 7 | 1 | J Peers B Soares | 7 | 6 | |||||||||||||||||||||
| WC | A Begemann D Brown | 7 | 64 | [13] | R Bopanna D Shapovalov | 5 | 3 | ||||||||||||||||||||
| WC | L Pouille J-W Tsonga | 5 | 77 | [15] | WC | L Pouille J-W Tsonga | 4 | 3 | |||||||||||||||||||
| R Bopanna D Shapovalov | 6 | 3 | [10] | R Bopanna D Shapovalov | 6 | 6 | |||||||||||||||||||||
| 3 | B Bryan M Bryan | 4 | 6 | [6] | R Bopanna D Shapovalov | 6 | 6 | ||||||||||||||||||||
| Alt |  M Berrettini M Fucsovics | 6 | 3 | [3] | N Kyrgios M Reid | 3 | 4 | ||||||||||||||||||||
 L Bambridge J O'Mara | 3 | 6 | [10] | L Bambridge J O'Mara | 3 | 4 | |||||||||||||||||||||
| N Kyrgios M Reid | 6 | 3 | [10] | N Kyrgios M Reid | 6 | 6 | |||||||||||||||||||||
| 2 |  N Mektić F Škugor | 4 | 6 | [4] | |||||||||||||||||||||||
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