Cadmium nitride

Cadmium nitride is a nitride of cadmium with the chemical formula Cd3N2.

Cadmium nitride
Identifiers
3D model (JSmol)
  • InChI=1S/3Cd.2N/q3*+2;2*-3
    Key: DSZUCHKZKXFZPK-UHFFFAOYSA-N
  • [Cd+2].[Cd+2].[Cd+2].[N-3].[N-3]
Properties
Cd3N2
Molar mass365.256 g·mol−1
Appearanceblack solid[1]
Density7.67 g·cm−3[1]
Related compounds
Other cations
Zinc nitride
Mercury nitride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Preparation

Cadmium nitride can be produced by thermal decomposition of cadmium amide at 180 °C:[1]

3 Cd(NH2)2 → Cd3N2 + 4 NH3

It can also be produced by thermal decomposition of cadmium azide at 210 °C.[2]

Properties

Cadmium nitride is a black solid that decomposes on contact with water and air. It will explode when reacting with dilute acids or alkalis. It is a crystal of inverse manganese(III) oxide structure with lattice constant a = 1079 pm.[1]

References