Isotopes of iridium

(Redirected from Iridium-193)

There are two natural isotopes of iridium (77Ir), and 37 radioisotopes, the most stable radioisotope being 192Ir with a half-life of 73.83 days, and many nuclear isomers, the most stable of which is 192m2Ir with a half-life of 241 years. All other isomers have half-lives under a year, most under a day. All isotopes of iridium are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.[4]

Isotopes of iridium (77Ir)
Main isotopes[1]Decay
abun­dancehalf-life (t1/2)modepro­duct
191Ir37.3%stable
192Irsynth73.827 dβ192Pt
ε192Os
192m2Irsynth241 yIT192Ir
193Ir62.7%stable
Standard atomic weight Ar°(Ir)

List of isotopes

Nuclide[5]
[n 1]
ZNIsotopic mass (Da)[6]
[n 2][n 3]
Half-life
[n 4]
Decay
mode

[n 5]
Daughter
isotope

[n 6][n 7]
Spin and
parity
[n 8][n 4]
Natural abundance (mole fraction)
Excitation energy[n 4]Normal proportionRange of variation
164Ir[7]7787163.99220(44)#<0.5 μsp?163Os2−#
164mIr270(110)# keV70(10) μsp (96%)163Os9+#
α (4%)160mRe
165Ir7788164.98752(23)#1.20+0.82
−0.74
 μs
[8]
p164Os(1/2+)
165mIr[9]~255 keV340(40) μsp (88%)164Os(11/2−)
α (12%)161mRe
166Ir7789165.98582(22)#10.5(22) msα (93%)162Re(2−)
p (7%)165Os
166mIr172(6) keV15.1(9) msα (98.2%)162Re(9+)
p (1.8%)165Os
167Ir7790166.981665(20)35.2(20) msα (48%)163Re1/2+
p (32%)166Os
β+ (20%)167Os
167mIr175.3(22) keV30.0(6) msα (80%)163Re11/2−
β+ (20%)167Os
p (.4%)166Os
168Ir7791167.97988(16)#161(21) msα164Re(2-)
β+ (rare)168Os
168mIr50(100)# keV125(40) msα164Re(9+)
169Ir7792168.976295(28)780(360) ms
[0.64(+46−24) s]
α165Re(1/2+)
β+ (rare)169Os
169mIr154(24) keV308(22) msα (72%)165Re(11/2−)
β+ (28%)169Os
170Ir7793169.97497(11)#910(150) ms
[0.87(+18−12) s]
β+ (64%)170Oslow#
α (36%)166Re
170mIr160(50)# keV440(60) msα (36%)166Re(8+)
β+170Os
IT170Ir
171Ir7794170.97163(4)3.6(10) s
[3.2(+13−7) s]
α (58%)167Re1/2+
β+ (42%)171Os
171mIr180(30)# keV1.40(10) s(11/2−)
172Ir7795171.970610(30)4.4(3) sβ+ (98%)172Os(3+)
α (2%)168Re
172mIr280(100)# keV2.0(1) sβ+ (77%)172Os(7+)
α (23%)168Re
173Ir7796172.967502(15)9.0(8) sβ+ (93%)173Os(3/2+,5/2+)
α (7%)169Re
173mIr253(27) keV2.20(5) sβ+ (88%)173Os(11/2−)
α (12%)169Re
174Ir7797173.966861(30)7.9(6) sβ+ (99.5%)174Os(3+)
α (.5%)170Re
174mIr193(11) keV4.9(3) sβ+ (99.53%)174Os(7+)
α (.47%)170Re
175Ir7798174.964113(21)9(2) sβ+ (99.15%)175Os(5/2−)
α (.85%)171Re
176Ir7799175.963649(22)8.3(6) sβ+ (97.9%)176Os
α (2.1%)172Re
177Ir77100176.961302(21)30(2) sβ+ (99.94%)177Os5/2−
α (.06%)173Re
178Ir77101177.961082(21)12(2) sβ+178Os
179Ir77102178.959122(12)79(1) sβ+179Os(5/2)−
180Ir77103179.959229(23)1.5(1) minβ+180Os(4,5)(+#)
181Ir77104180.957625(28)4.90(15) minβ+181Os(5/2)−
182Ir77105181.958076(23)15(1) minβ+182Os(3+)
183Ir77106182.956846(27)57(4) minβ+ ( 99.95%)183Os5/2−
α (.05%)179Re
184Ir77107183.95748(3)3.09(3) hβ+184Os5−
184m1Ir225.65(11) keV470(30) μs3+
184m2Ir328.40(24) keV350(90) ns(7)+
185Ir77108184.95670(3)14.4(1) hβ+185Os5/2−
186Ir77109185.957946(18)16.64(3) hβ+186Os5+
186mIr0.8(4) keV1.92(5) hβ+186Os2−
IT (rare)186Ir
187Ir77110186.957363(7)10.5(3) hβ+187Os3/2+
187m1Ir186.15(4) keV30.3(6) msIT187Ir9/2−
187m2Ir433.81(9) keV152(12) ns11/2−
188Ir77111187.958853(8)41.5(5) hβ+188Os1−
188mIr970(30) keV4.2(2) msIT188Ir7+#
β+ (rare)188Os
189Ir77112188.958719(14)13.2(1) dEC189Os3/2+
189m1Ir372.18(4) keV13.3(3) msIT189Ir11/2−
189m2Ir2333.3(4) keV3.7(2) ms(25/2)+
190Ir77113189.9605460(18)11.78(10) dEC190Os4−
β+ (<0.002%)[1]
190m1Ir26.1(1) keV1.120(3) hIT190Ir(1−)
190m2Ir36.154(25) keV>2 μs(4)+
190m3Ir376.4(1) keV3.087(12) h(11)−
191Ir77114190.9605940(18)Observationally Stable[n 9]3/2+0.373(2)
191m1Ir171.24(5) keV4.94(3) sIT191Ir11/2−
191m2Ir2120(40) keV5.5(7) s
192Ir77115191.9626050(18)73.827(13) dβ (95.24%)192Pt4+
EC (4.76%)192Os
192m1Ir56.720(5) keV1.45(5) minIT (98.25%)192Ir1−
β (1.75%)192Pt
192m2Ir168.14(12) keV241(9) yIT192Ir(11−)
193Ir77116192.9629264(18)Observationally Stable[n 10]3/2+0.627(2)
193mIr80.240(6) keV10.53(4) dIT193Ir11/2−
194Ir77117193.9650784(18)19.28(13) hβ194Pt1−
194m1Ir147.078(5) keV31.85(24) msIT194Ir(4+)
194m2Ir370(70) keV171(11) d(10,11)(−#)
195Ir77118194.9659796(18)2.5(2) hβ195Pt3/2+
195mIr100(5) keV3.8(2) hβ (95%)195Pt11/2−
IT (5%)195Ir
196Ir77119195.96840(4)52(1) sβ196Pt(0−)
196mIr210(40) keV1.40(2) hβ (99.7%)196Pt(10,11−)
IT196Ir
197Ir77120196.969653(22)5.8(5) minβ197Pt3/2+
197mIr115(5) keV8.9(3) minβ (99.75%)197Pt11/2−
IT (.25%)197Ir
198Ir77121197.97228(21)#8(1) sβ198Pt
199Ir77122198.97380(4)7(5) sβ199Pt3/2+#
199mIr130(40)# keV235(90) nsIT199Ir11/2−#
200Ir77123199.976800(210)#43(6) sβ200Pt(2-, 3-)
201Ir77124200.978640(210)#21(5) sβ201Pt(3/2+)
202Ir77125201.981990(320)#11(3) sβ202Pt(2-)
202mIr2000(1000)# keV3.4(0.6) μsIT202Ir
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Iridium-192

Iridium-192 (symbol 192Ir) is a radioactive isotope of iridium, with a half-life of 73.83 days.[10] It decays by emitting beta (β) particles and gamma (γ) radiation. About 96% of 192Ir decays occur via emission of β and γ radiation, leading to 192Pt. Some of the β particles are captured by other 192Ir nuclei, which are then converted to 192Os. Electron capture is responsible for the remaining 4% of 192Ir decays.[11] Iridium-192 is normally produced by neutron activation of natural-abundance iridium metal.[12]

Iridium-192 is a very strong gamma ray emitter, with a gamma dose-constant of approximately 1.54 μSv·h−1·MBq−1 at 30 cm, and a specific activity of 341 TBq·g−1 (9.22 kCi·g−1).[13][14] There are seven principal energy packets produced during its disintegration process ranging from just over 0.2 to about 0.6 MeV.

The 192m2Ir isomer is unusual, both for its long half-life for an isomer, and that said half-life greatly exceeds that of the ground state of the same isotope.

References

External links