Terbium phosphide is an inorganic compound of terbium and phosphorus with the chemical formula TbP.[1][2]
![]() | |
Names | |
---|---|
Other names Terbium monophosphide, phosphanylidyneterbium | |
Identifiers | |
3D model (JSmol) | |
EC Number |
|
PubChem CID | |
| |
| |
Properties | |
PTb | |
Molar mass | 189.899 |
Appearance | Black crystals |
Density | 6.82 g/cm3 |
Structure | |
Cubic | |
Related compounds | |
Other anions | Terbium nitride Terbium arsenide Terbium antimonide Terbium bismuthide |
Other cations | Gadolinium phosphide Dysprosium phosphide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Synthesis
TbP can be obtained by the reaction of terbium and red phosphorus at 800–1000 °C:
- 4 Tb + P4 → 4 TbP
The compound can also be obtained by the reaction of sodium phosphide and anhydrous terbium chloride at 700~800 °C.[3]
Physical properties
TbP undergoes a phase transition at 40 GPa from a NaCl-structure to a CsCl-structure.[4] The compound can be sintered with zinc sulfide to make a green phosphor layer.[5]
TbP forms crystals of a cubic system, space group Fm3m.[6]
Uses
The compound is a semiconductor used in high power, high frequency applications and in laser diodes and other photo diodes.[1]
References
🔥 Top keywords: Main PageSpecial:SearchPage 3Wikipedia:Featured picturesHouse of the DragonUEFA Euro 2024Bryson DeChambeauJuneteenthInside Out 2Eid al-AdhaCleopatraDeaths in 2024Merrily We Roll Along (musical)Jonathan GroffJude Bellingham.xxx77th Tony AwardsBridgertonGary PlauchéKylian MbappéDaniel RadcliffeUEFA European Championship2024 ICC Men's T20 World CupUnit 731The Boys (TV series)Rory McIlroyN'Golo KantéUEFA Euro 2020YouTubeRomelu LukakuOpinion polling for the 2024 United Kingdom general electionThe Boys season 4Romania national football teamNicola CoughlanStereophonic (play)Gene WilderErin DarkeAntoine GriezmannProject 2025