Drafts
- Silicon-oxygen bond
- Ruthenium(II) iodide, RuI2, blue according to G&E p. 1083. Binary Ru(II) halides not well characterised according to Housecroft p. 780.
- Ruthenium(III) iodide, RuI3, black according to G&E p. 1083. Synthesis is RuO4 + aq HI → RuI3 and adopts extended structure with octahedral Ru(III) per Housecroft p. 779.
Chalcogen oxohalides
Existing content
- Oxohalide#Main group elements has a section on chalcogen oxohalides
- Nothing at chalcogen
- Brief mentions at Sulfur#Halogenation
- Brief mentions at Selenium#Halogen compounds
- Tellurium#Halides mentions the –OTeF5 group and a few compounds in which it occurs
Table of chalcogen oxohalides
Stoichiometry | Oxidation state of Z | Sulfur | Selenium | Tellurium |
---|---|---|---|---|
References | [1][2] | [3] | [3] | |
ZOX2 | +4 | SOF2, SOFCl, SOCl2, SOBr2 | SeOF2, SeOCl2, SeOBr2 | |
ZO2X2 | +6 | SO2F2, SO2FCl, SO2Cl2, SO2Br2 | SeO2F2 | |
ZOX4 | +6 | (SeOF4)2 i.e. Se2O2F8 | (TeOF4)2 i.e. Te2O2F8 | |
X5ZOX | +6 | F5SeOF | F5TeOF | |
X5ZOZX5 | +6 | F5SOSF5 | F5SeOSeF5 | F5TeOTeF5 |
X5ZOOZX5 | +6 | F5SeOOSeF5 | ||
Z3O2X14 | +6 | Te3O2F14 | ||
Z6O5X26 | +6 | Te6O5F26 | ||
X4Z(OZX5)2 | +6 | cis- and trans-F4Te(OTeF5)2 | ||
X2Z(OZX5)4 | +6 | cis- and trans-F2Te(OTeF5)4 | ||
XZ(OZX5)5 | +6 | FTe(OTeF5)5 | ||
Z(OZX5)6 | +6 | Te(OTeF5)6 |
Categories
- Category:Oxohalides
- Category:Thionyl compounds
- Category:Sulfuryl compounds
- Category:Sulfur(IV) compounds
- Category:Sulfur(VI) compounds
- Category:Inorganic sulfur compounds
- Category:Selenium(IV) compounds
- Category:Selenium(VI) compounds
- Category:Tellurium(VI) compounds
See also
Chalcogen halides
Stoichiometry | Oxidation state of Z | Oxygen | Sulfur | Selenium | Tellurium | Polonium |
---|---|---|---|---|---|---|
Z2X | +½ | Te2Cl Te2Br Te2I | ||||
Z3X2 | +⅔ | Te3Cl2 | ||||
ZX | +1 | TeI | ||||
Z2X2 | +1 | O2F2 O2Cl2 | S2F2 S2Cl2 S2Br2 | Se=SeF2 Se2F2 Se2Cl2 Se2Br2 Se2I2 | Te2F2 Te2Cl2 Te2Br2 | |
ZX2 | +2 | OF2 OCl2 OBr2 OI2 | SF2 SCl2 SBr2 | SeF2 SeCl2 SeBr2 | TeF2 TeCl2 TeBr2 | PoCl2 PoBr2 PoI2 |
ZX4 | +4 | SF4 SCl4 | SeF4 SeCl4 SeBr4 | TeF4 TeCl4 TeBr4 TeI4 | PoF4 PoCl4 PoBr4 PoI4 | |
ZX6 | +6 | SF6 | SeF6 | TeF6 | PoF6 |
Lanthanide compound photos
La | Ce | Pr | Nd | Pm | Sm | Eu | Gd | Tb | Dy | Ho | Er | Tm | Yb | Lu | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Ln2O3 | |||||||||||||||
Ln(OH)3 | |||||||||||||||
LnF3 | |||||||||||||||
LnCl3 | |||||||||||||||
LnBr3 | |||||||||||||||
LnI3 | |||||||||||||||
Ln(NO3)3 | |||||||||||||||
Ln2(SO4)3 | |||||||||||||||
Ln(OAc)3 |
Deltahedral boron clusters
|
See also
Monochlorides
1 H | 2 He | ||||||||||||||||||
3 LiCl | 4 Be | 5 B | 6 C | 7 N | 8 O | 9 FCl | 10 Ne | ||||||||||||
11 NaCl | 12 Mg | 13 Al | 14 Si | 15 P | 16 S2Cl2 | 17 Cl2 | 18 Ar | ||||||||||||
19 KCl | 20 Ca | 21 Sc | 22 Ti | 23 V | 24 Cr | 25 Mn | 26 Fe | 27 Co | 28 Ni | 29 CuCl | 30 Zn | 31 Ga | 32 Ge | 33 As | 34 Se2Cl2 | 35 BrCl | 36 Kr | ||
37 RbCl | 38 Sr | 39 Y | 40 Zr | 41 Nb | 42 Mo | 43 Tc | 44 Ru | 45 Rh | 46 Pd | 47 AgCl | 48 Cd | 49 InCl | 50 Sn | 51 Sb | 52 Te | 53 ICl | 54 Xe | ||
55 CsCl | 56 Ba | 71 Lu | 72 Hf | 73 Ta | 74 W | 75 Re | 76 Os | 77 Ir | 78 Pt | 79 AuCl | 80 Hg2Cl2 | 81 TlCl | 82 Pb | 83 Bi | 84 Po | 85 AtCl | 86 Rn | ||
87 Fr | 88 Ra | 103 Lr | 104 Rf | 105 Db | 106 Sg | 107 Bh | 108 Hs | 109 Mt | 110 Ds | 111 Rg | 112 Cn | 113 Nh | 114 Fl | 115 Mc | 116 Lv | 117 Ts | 118 Og | ||
57 La | 58 Ce | 59 Pr | 60 Nd | 61 Pm | 62 Sm | 63 Eu | 64 Gd | 65 Tb | 66 Dy | 67 Ho | 68 Er | 69 Tm | 70 Yb | ||||||
89 Ac | 90 Th | 91 Pa | 92 U | 93 Np | 94 Pu | 95 Am | 96 Cm | 97 Bk | 98 Cf | 99 Es | 100 Fm | 101 Md | 102 No |
Legend: |
---|
other |
unknown or uncertain |
Dichlorides
- Cadmium chloride (CdCl2) structure
- Cadmium iodide (CdI2) structure
- Fluorite (CaF2) structure
- Antifluorite structure, e.g. Na2O
- Rutile (TiO2) structure
- Antirutile structure, e.g. Ti2N
- Beryllium bromide (BeBr2) structure
- β-Cristobalite (SiO2) structure, e.g. BeF2
Trichlorides
1 H | 2 He | ||||||||||||||||||
3 Li | 4 Be | 5 BCl3 | 6 C | 7 NCl3 | 8 O | 9 F | 10 Ne | ||||||||||||
11 Na | 12 Mg | 13 AlCl3 | 14 Si | 15 PCl3 | 16 S | 17 Cl | 18 Ar | ||||||||||||
19 K | 20 Ca | 21 ScCl3 | 22 Ti | 23 VCl3 | 24 CrCl3 | 25 Mn | 26 FeCl3 | 27 Co | 28 Ni | 29 Cu | 30 Zn | 31 GaCl3 | 32 Ge | 33 AsCl3 | 34 Se | 35 Br | 36 Kr | ||
37 Rb | 38 Sr | 39 YCl3 | 40 ZrCl3 | 41 Nb | 42 α-MoCl3 | 43 Tc | 44 RuCl3 | 45 RhCl3 | 46 Pd | 47 Ag | 48 Cd | 49 InCl3 | 50 Sn | 51 SbCl3 | 52 Te | 53 ICl3 | 54 Xe | ||
55 Cs | 56 Ba | 71 LuCl3 | 72 Hf | 73 Ta | 74 WCl3 | 75 ReCl3 | 76 Os | 77 α-IrCl3 | 78 Pt | 79 AuCl3 | 80 Hg | 81 Tl | 82 Pb | 83 BiCl3 | 84 Po | 85 At | 86 Rn | ||
87 Fr | 88 Ra | 103 Lr | 104 Rf | 105 Db | 106 Sg | 107 Bh | 108 Hs | 109 Mt | 110 Ds | 111 Rg | 112 Cn | 113 Nh | 114 Fl | 115 Mc | 116 Lv | 117 Ts | 118 Og | ||
57 LaCl3 | 58 CeCl3 | 59 PrCl3 | 60 NdCl3 | 61 PmCl3 | 62 SmCl3 | 63 EuCl3 | 64 GdCl3 | 65 TbCl3 | 66 DyCl3 | 67 HoCl3 | 68 ErCl3 | 69 TmCl3 | 70 YbCl3 | ||||||
89 AcCl3 | 90 Th | 91 Pa | 92 UCl3 | 93 NpCl3 | 94 PuCl3 | 95 AmCl3 | 96 Cm | 97 Bk | 98 Cf | 99 Es | 100 Fm | 101 Md | 102 No |
Legend: |
---|
other |
II |
III |
IV |
V |
VI |
IX |
X |
unknown or uncertain |
🔥 Top keywords: Main PageSpecial:SearchWikipedia:Featured picturesYasukeHarrison ButkerRobert FicoBridgertonCleopatraDeaths in 2024Joyce VincentXXXTentacionHank AdamsIt Ends with UsYouTubeNew Caledonia2024 Indian general electionHeeramandiDarren DutchyshenSlovakiaKingdom of the Planet of the ApesAttempted assassination of Robert FicoLawrence WongBaby ReindeerXXX: Return of Xander CageThelma HoustonFuriosa: A Mad Max SagaMegalopolis (film)Richard GaddKepler's SupernovaWicked (musical)Sunil ChhetriXXX (2002 film)Ashley MadisonAnya Taylor-JoyPlanet of the ApesNava MauYoung SheldonPortal:Current eventsX-Men '97