Palladium

chemical element wi the atomic nummer o 46

Palladium is a chemical element wi the chemical seembol Pd an an atomic nummer o 46. It is a rare an lustrous sillery-white metal discovered in 1803 bi William Hyde Wollaston. He named it efter the asteroid Pallas, that wis itsel named efter the epithet o the Greek goddess Athena, acquired bi her whan she slew Pallas. Palladium, platinum, rhodium, ruthenium, iridium an osmium fairm a group o elements referred tae as the platinum group metals (PGMs). Thae hae seemilar chemical properties, but palladium haes the lawest meltin pynt an is the least dense o thaim.

Palladium, 46Pd
Template:Infobox element/symbol-to-top-image/alt
Palladium
Pronunciation/pəˈldiəm/ (pə-LAY-dee-əm)
Appearancesillery white
Standard atomic weight Ar, std(Pd)106.42(1)[1]
Palladium in the periodic cairt
HydrogenHelium
LithiumBerylliumBoronCarbonNitrogenOxygenFluorineNeon
SodiumMagnesiumAluminiumSiliconPhosphorusSulfurChlorineArgon
PotassiumCalciumScandiumTitaniumVanadiumChromiumManganeseAirnCobaltNickelCapperZincGalliumGermaniumArsenicSeleniumBromineKrypton
RubidiumStrontiumYttriumZirconiumNiobiumMolybdenumTechnetiumRutheniumRhodiumPalladiumSiller (element)CadmiumIndiumTinAntimonyTelluriumIodineXenon
CaesiumBariumLanthanumCeriumPraseodymiumNeodymiumPromethiumSamariumEuropiumGadoliniumTerbiumDysprosiumHolmiumErbiumThuliumYtterbiumLutetiumHafniumTantalumTungstenRheniumOsmiumIridiumPlatinumGowdMercur (element)ThalliumLeid (element)BismuthPoloniumAstatineRadon
FranciumRadiumActiniumThoriumProtactiniumUraniumNeptuniumPlutoniumAmericiumCuriumBerkeliumCaliforniumEinsteiniumFermiumMendeleviumNobeliumLawrenciumRutherfordiumDubniumSeaborgiumBohriumHassiumMeitneriumDarmstadtiumRoentgeniumCoperniciumUnuntriumFleroviumUnunpentiumLivermoriumUnunseptiumUnunoctium
Ni

Pd

Pt
rhodium ← palladiumsiller
Atomic nummer (Z)46
Groupgroup 10
Periodperiod 5
Blockd-block
Element category  Transeetion metal
Electron confeeguration[Kr] 4d10
Electrons per shell2, 8, 18, 18
Pheesical properties
Phase at STPsolit
Meltin pynt1828.05 K ​(1554.9 °C, ​2830.82 °F)
Bylin pynt3236 K ​(2963 °C, ​5365 °F)
Density (near r.t.)12.023 g/cm3
when liquid (at m.p.)10.38 g/cm3
Heat o fusion16.74 kJ/mol
Heat o vapourisation362 kJ/mol
Molar heat capacity25.98 J/(mol·K)
Vapour pressur
P (Pa)1101001 k10 k100 k
at T (K)172118972117239527533234
Atomic properties
Oxidation states0, +1, +2, +3, +4 (a mildly basic oxide)
ElectronegativityPauling scale: 2.20
Atomic radiusempirical: 137 pm
Covalent radius139±6 pm
Van der Waals radius163 pm
Colour lines in a spectral range
Colour lines in a spectral range
Spectral lines o palladium
Ither properties
Naitural occurrenceprimordial
Creestal structur ​face-centred cubic (fcc)
Face-centered cubic creestal structur for palladium
Speed o soond thin rod3070 m/s (at 20 °C)
Thermal expansion11.8 µm/(m·K) (at 25 °C)
Thermal conductivity71.8 W/(m·K)
Electrical resistivity105.4 n Ω·m (at 20 °C)
Magnetic orderinparamagnetic[2]
Young's modulus121 GPa
Shear modulus44 GPa
Bulk modulus180 GPa
Poisson ratio0.39
Mohs haurdness4.75
Vickers haurdness461 MPa
Brinell haurdness310 MPa
CAS Nummer7440-05-3
History
DiskiveryWilliam Hyde Wollaston (1803)
First isolationWilliam Hyde Wollaston (1803)
Main isotopes o palladium
Iso­topeAbun­danceHauf-life (t1/2)Decay modePro­duct
100Pdsyn3.63 dε100Rh
γ-
102Pd1.02%stable
103Pdsyn16.991 dε103Rh
104Pd11.14%stable
105Pd22.33%stable
106Pd27.33%stable
107Pdtrace6.5×106 yβ107Ag
108Pd26.46%stable
110Pd11.72%>6×1017 yββ110Cd
| references

Ower hauf o the supply o palladium an its congener platinum gangs intae catalytic converters, that convert up tae 90% o harmfu gases frae auto exhaust (hydrocarbons, carbon monoxide, an nitrogen dioxide) intae less-harmful substances (nitrogen, carbon dioxide an watter vapor). Palladium is uised in electronics, dentistry, medicine, hydrogen purification, chemical applications, groundwatter treatment an jewelry. Palladium plays a key role in the technology uised for fuel cells, that combine hydrogen an oxygen tae produce electricity, heat, an watter.

Ore deposits o palladium an ither PGMs are rare, an the maist extensive deposits hae been foond in the norite belt o the Bushveld Igneous Complex coverin the Transvaal Basin in Sooth Africae, the Stillwatter Complex in Montana, Unitit States, the Thunder Bay Destrict o Ontario, Canadae, an the Norilsk Complex in Roushie. Recyclin is a soorce o palladium, maistly frae scrapped catalytic converters. The numerous applications an leemitit supply soorces o palladium result in the metal attractin considerable investment interest.

References

Freemit airtins