Actinium

chemical element with the atomic number of 89

Actinium is chemical element 89 on the periodic table. Its symbol is Ac. Actinium's mass is 227 g/mol.

Actinium, 00Ac
Actinium
Pronunciation/ækˈtɪniəm/ (ak-TIN-ee-əm)
Appearancesilvery-white, glowing with an eerie blue light;[1] sometimes with a golden cast[2]
Mass number[227]
Actinium in the periodic table
HydrogenHelium
LithiumBerylliumBoronCarbonNitrogenOxygenFluorineNeon
SodiumMagnesiumAluminiumSiliconPhosphorusSulfurChlorineArgon
PotassiumCalciumScandiumTitaniumVanadiumChromiumManganeseIronCobaltNickelCopperZincGalliumGermaniumArsenicSeleniumBromineKrypton
RubidiumStrontiumYttriumZirconiumNiobiumMolybdenumTechnetiumRutheniumRhodiumPalladiumSilverCadmiumIndiumTinAntimonyTelluriumIodineXenon
CaesiumBariumLanthanumCeriumPraseodymiumNeodymiumPromethiumSamariumEuropiumGadoliniumTerbiumDysprosiumHolmiumErbiumThuliumYtterbiumLutetiumHafniumTantalumTungstenRheniumOsmiumIridiumPlatinumGoldMercury (element)ThalliumLeadBismuthPoloniumAstatineRadon
FranciumRadiumActiniumThoriumProtactiniumUraniumNeptuniumPlutoniumAmericiumCuriumBerkeliumCaliforniumEinsteiniumFermiumMendeleviumNobeliumLawrenciumRutherfordiumDubniumSeaborgiumBohriumHassiumMeitneriumDarmstadtiumRoentgeniumCoperniciumNihoniumFleroviumMoscoviumLivermoriumTennessineOganesson
La

Ac

(Uqt)
radiumactiniumthorium
Groupf-block groups (no number)
Periodperiod 7
Block  f-block
Electron configuration[Rn] 6d1 7s2
Electrons per shell2, 8, 18, 32, 18, 9, 2
Physical properties
Phase at STPsolid
Melting point1500 K ​(1227 °C, ​2240 °F) (estimated)[2]
Boiling point3500±300 K ​(3200±300 °C, ​5800±500 °F) (extrapolated)[2]
Density (near r.t.)10 g/cm3
Heat of fusion14 kJ/mol
Heat of vaporization400 kJ/mol
Molar heat capacity27.2 J/(mol·K)
Atomic properties
Oxidation states+3 (a strongly basic oxide)
ElectronegativityPauling scale: 1.1
Ionization energies
  • 1st: 499 kJ/mol
  • 2nd: 1170 kJ/mol
  • 3rd: 1900 kJ/mol
  • (more)
Covalent radius215 pm
Color lines in a spectral range
Spectral lines of actinium
Other properties
Natural occurrencefrom decay
Crystal structureface-centered cubic (fcc)
Face-centered cubic crystal structure for actinium
Thermal conductivity12 W/(m⋅K)
CAS Number7440-34-8
History
Discovery and first isolationFriedrich Oskar Giesel (1902)
Named byAndré-Louis Debierne (1899)
Isotopes of actinium
Main isotopes[3]Decay
abun­dancehalf-life (t1/2)modepro­duct
225Actrace9.919 dα221Fr
14C211Bi
226Acsynth29.37 hβ226Th
ε226Ra
α222Fr
227Actrace21.772 yβ227Th
α223Fr
 Category: Actinium
| references

Actinium is a silver radioactive, solid metal in actinide group. It is so radioactive that it glows in the dark. Even a small amount of actinium is dangerous to people.

History

Actinium was discovered in 1899 by André-Louis Debierne, a French chemist. In 1899, Debierne described the substance as similar to titanium[4] and (in 1900) as similar to thorium.[5]

Properties

Actinium is a soft, silvery-white, radioactive metal.[6][7] Its estimated shear modulus is similar to that of lead. Because its strong radioactivity, actinium glows in the dark with a pale blue light.[8]

Actinium reacts quickly with oxygen and moisture in air forming a white coating of actinium oxide that stops the actinium from oxidizing.[6]

Isotopes

Actinium that is found in nature is made up of two radionuclides 227Ac and 228Ac. Thirty-six radionuclides of actinium have been found. The most stable is 227Ac which has a half-life of 21.772 years. The shortest-lived known isotope of actinium is 217Ac which has a half-life of 69 nanoseconds.

Occurence

Actinium is only found in trace amounts in uranium ores. For example, one tonne of uranium ore contains about 0.2 milligrams of 227Ac. Thorium ores contain about 5 nanograms of 228Ac per one tonne of thorium.[9]

Uses

225Ac is now being studied for use in cancer treatments. 227Ac is studied for use as an active element of radioisotope thermoelectric generators. 225Ac is used in medicine to make 213Bi in a reusable generator. It can be used in radiation therapy.[10][11][12]

References